A recent study led by Olivier Mousis from the University of Franche-Comté in France examined how Titan’s methane rainfall would interact with icy materials within underground reservoirs. They found that the formation of materials called clathrates changes the chemical composition of the rainfall runoff that charges these hydrocarbon “aquifers.” This process leads to the formation of reservoirs of propane and ethane that may feed into some rivers and lakes.
“We knew that a significant fraction of the lakes on Titan’s surface might possibly be connected with hidden bodies of liquid beneath Titan’s crust, but we just didn’t know how they would interact,” said Mousis. “Now, we have a better idea of what these hidden lakes or oceans could be like.”
Mousis and colleagues at Cornell University in Ithaca, New York, and NASA’s Jet Propulsion Laboratory (JPL) in Pasadena, California, modeled how a subsurface reservoir of liquid hydrocarbons would diffuse, or spread, through Titan’s porous icy crust. They found that at the bottom of the original reservoir, which contains methane from rainfall, a second reservoir would slowly form. This secondary reservoir would be composed of clathrates.
Clathrates are compounds in which water forms a crystal structure with small cages that trap other substances like methane and ethane. Clathrates that contain methane are found on Earth in some polar and ocean sediments. On Titan, the surface pressure and temperature should allow clathrates to form when liquid hydrocarbons come into contact with water ice, which is a major component of the moon’s crust. These clathrate layers could remain stable as far down as several miles below Titan’s surface.
One of the peculiar properties of clathrates is that they trap and split molecules into a mix of liquid and solid phases in a process called fractionation. Titan’s subsurface clathrate reservoirs would interact with and fractionate the liquid methane from the original underground hydrocarbon lake, slowly changing its composition. Eventually the original methane aquifer would be turned into a propane or ethane aquifer.
“Our study shows that the composition of Titan’s underground liquid reservoirs can change significantly through their interaction with the icy subsurface, provided the reservoirs are cut off from the atmosphere for some period of time,” said Mathieu Choukroun of JPL.
Importantly, the chemical transformations taking place underground would affect Titan’s surface. Lakes and rivers fed by springs from propane or ethane subsurface reservoirs would show the same kind of composition, whereas those fed by rainfall would be different and contain a significant fraction of methane. This means researchers could examine the composition of Titan’s surface lakes to learn something about what is happening deep underground, said Mousis.